The asymmetric Favorskii rearrangement: A synthesis of optically active α-alkyl amides from aldehydes and (-)-1-chloroalkyl p-tolyl sulfoxide

DOI: 10.1016/S0040-4039(00)74098-6

Source and publish data:

Tetrahedron Letters p. 4823 - 4826 (1993)

Update date:2022-08-05

Topics:

Authors:

Satoh Satoh

Motohashi

Kimura Kimura

Tokutake

Yamakawa

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Article abstract of DOI:10.1016/S0040-4039(00)74098-6

The first asymmetric Favorskii rearrangement is described. Optically active α-alkyl amides of enantiomeric excess up to 94% were realized from aldehydes and optically active (-)-1-chloroalkyl p-tolyl sulfoxides via the Favorskii rearrangement of optically

Full text of DOI:10.1016/S0040-4039(00)74098-6

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