An Approach to Features Responsible for the Obtention of High e.e. with a Highly Enantioselective NADH Model

DOI: 10.1016/S0040-4020(01)82373-5

Source and publish data:

Tetrahedron p. 5237 - 5246 (1993)

Update date:2022-08-04

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Authors:

Combret, Yves

Duflos, Jack

Dupas, Georges

Bourguignon, Jean

Queguiner, Guy

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Article abstract of DOI:10.1016/S0040-4020(01)82373-5

A study of the reactivity of several NADH models with free, restricted or suppressed rotating ability of the amide carbonyl group suggests that the main factor responsible for the high e.e. obtained (94percent) with a cyclized reagent is an entropy featur

Full text of DOI:10.1016/S0040-4020(01)82373-5

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