Journal of Organometallic Chemistry p. 103 - 106 (1997)
Update date:2022-07-28
Topics:
Walter, Olaf
Buechner, Michael
Huttner, Gottfried
The tripodal triphosphide H3CC[CH2P(Ph)(Li)]3 reacts with MeSiCl3 to yield the triphosphinosilane H3CC[CH2P(Ph)]3SiMe, 2a. The analogous reaction with PBr3 produces the triphosphinophosphine H3CC[CH2P(Ph)]3P, 2b. The bicyclo[2.2.2]octane-type cage structure of 2 is revealed by NMR data as well as X-ray analyses. 2b is one of the rare examples of a compound with mere C3-symmetry.
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Doi:10.1016/S0040-4039(03)01791-X
(2003)Doi:10.1016/S0022-328X(00)89258-X
(1972)Doi:10.1016/S0957-4166(03)00483-X
(2003)Doi:10.1055/s-2006-944222
(2006)Doi:10.1023/A:1023931428206
(2003)Doi:10.1055/s-1976-24162
(1976)
