Journal of Organometallic Chemistry p. 103 - 106 (1997)
Update date:2022-07-28
Topics:
Walter, Olaf
Buechner, Michael
Huttner, Gottfried
The tripodal triphosphide H3CC[CH2P(Ph)(Li)]3 reacts with MeSiCl3 to yield the triphosphinosilane H3CC[CH2P(Ph)]3SiMe, 2a. The analogous reaction with PBr3 produces the triphosphinophosphine H3CC[CH2P(Ph)]3P, 2b. The bicyclo[2.2.2]octane-type cage structure of 2 is revealed by NMR data as well as X-ray analyses. 2b is one of the rare examples of a compound with mere C3-symmetry.
Liaoning Yufeng Chemical Co.,Ltd.
Contact:86-0419-3418888
Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Contact:+86-731-84427351
Address:154 JIANXIANG SOUTH ROAD
Shanghai Egoal Chemical Co.,Ltd
Contact:+86-21-50333091
Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
Weifang Adde Economic And Trade Co.,LTD.
Contact:86-536-8885548
Address:Room 1402,Wanda Plaza B Block,No.958,Yuanfei Road,Kuiwen District
Contact:+86-021-50792271
Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Doi:10.1016/S0040-4039(03)01791-X
(2003)Doi:10.1016/S0022-328X(00)89258-X
(1972)Doi:10.1016/S0957-4166(03)00483-X
(2003)Doi:10.1055/s-2006-944222
(2006)Doi:10.1023/A:1023931428206
(2003)Doi:10.1055/s-1976-24162
(1976)
