Synthesis of Chiral Lithium Dialkoxyaminoborohydrides

DOI: 10.1016/0040-4020(95)00101-D

Source and publish data:

Tetrahedron p. 3803 - 3812 (1995)

Update date:2022-08-05

Topics:

Authors:

Dubois, Laurent

Fiaud, Jean-Claude

Kagan, Henri B.

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Article abstract of DOI:10.1016/0040-4020(95)00101-D

A convenient synthesis of chiral dialkoxyaminoborohydrides from borane and some diethanolamines is described.Tis is a novel class of reducing agents which react with acetophenone to afford α-methyl benzyl alcohol in good yields but in low ee's.

Full text of DOI:10.1016/0040-4020(95)00101-D

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Product name:bis <(1R)-1-hydroxyphenyl-ethan-2-yl> amine

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