Diastereoselective synthesis of a highly functionalized cyclohexene embedded with a quaternary stereogenic centre by self Diels-Alder dimerization of a [3]dendralene attached to a (-)-menthol auxiliary

DOI: 10.1016/j.tetasy.2013.11.005

Source and publish data:

Tetrahedron Asymmetry p. 57 - 62 (2014)

Update date:2022-08-05

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Authors:

Singh, Rekha

Ghosh, Sunil K.

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Article abstract of DOI:10.1016/j.tetasy.2013.11.005

A novel route to a chiral functionalized [3]dendralene attached to a (-)-menthol auxiliary has been developed, which involves a dimethylsulfonium methylide mediated olefination of a substituted ethenylidene phosphonoacetate (-)-menthyl ester, followed by

Full text of DOI:10.1016/j.tetasy.2013.11.005

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