A highly selective protocol for the deprotection of BOC-protected amides and carbamates

DOI: 10.1016/S0040-4039(00)61498-3

Source and publish data:

Tetrahedron Letters p. 7873 - 7876 (1993)

Update date:2022-08-03

Topics:

Authors:

Stafford, Jeffrey A.

Brackeen, Marcus F.

Karanewsky, Donald S.

Valvano, Nicole L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)61498-3

A BOC-protected amide or carbamate undergoes mild and selective deprotection by treatment with catalytic Mg(ClO₄)₂ in acetonitrile. Simple BOC-protected amines are not affected by these conditions.

Full text of DOI:10.1016/S0040-4039(00)61498-3

Products guided by the article

Product name:benzyl cytosine(Boc) acetate

Cas No:154409-68-4

R&D Labs maybe for 154409-68-4

Wuxi Innopal International Trade CO.,LTD

Contact:+86-510-80711901-8003

Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China
SEA BRGIHT INDUSTRY CO.,LIMITED

Contact:0086 755 8622 3990

Address:Rm 17B3,GuangCaiXinTianDi Bldg,GuiMiao Rd,NanShan District,Shenzhen,China
Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China

Relevant to this article

Zinc(II), ruthenium(II), rhodium(III), palladium(II), silver(I), platinum(II) and MoO 2 2 + complexes of 2-(2′-hydroxy-5′- methylphenyl)-benzotriazole as simple or primary ligand and 2,2′- bipyridyl, 9,10-phenanthroline or triphenylphosphine as secondary ligands: Structure and anticancer activity

Doi:10.1016/j.molstruc.2013.11.039
(2014)
A ruthenium(II) complex having a ligand undergoing partial C = N cleavage and unusual double-bond shift and nonchirality

Doi:10.1016/j.inoche.2013.11.046
(2014)
The synthesis of 4,7-disubstituted-2H-benzo[b][1,4]-oxazin-3(4H)-ones using Smiles rearrangement and their in vitro evaluation as platelet aggregation inhibitors

Doi:10.1016/j.bmcl.2014.02.014
(2014)
Synthesis based on cyclohexadienes: Part 10¹ synthesis of 5,5'-dimethyl-7-methoxy-4-oxatricyclo[4.3.1.0^3,7]decan-2-ones

Doi:10.1016/S0040-4020(01)86976-3
(1994)
Synthesis and Characterization of Models for the 2,4,5-Trihydroxyphenylalanine (TOPA)-Derived Cofactor of Mammalian Copper Amine Oxidases, and Initial Amine Reactivity Studies

Doi:10.1021/jo00088a023
(1994)
Asymmetric synthesis. XXX. Synthesis of 3-substituted piperidines from chiral non-racemic lactams

Doi:10.1016/S0040-4039(00)77162-0
(1994)

Article Doi