
Chemistry Letters p. 619 - 622 (1994)
Update date:2022-08-03
Topics:
Fujihara, Hisashi
Higuchi, Yasuhiro
Mima, Hisatomo
Furukawa, Naomichi
The cyclic voltammogram of a new trisselenide, 2,6-bis(phenylselenomethyl)phenyl phenyl selenide (1), showed the reversible electrochemical oxidation with low oxidation potential which is attributed to the three-center selenium participation.The monoselenoxide of 1 was formed in the hydrolysis of concd H2SO4 solution of 1, while the MCPBA oxidation of 1 gave a mixture of the corresponding mono- and bisselenoxides.
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