Short-step asymmetric syntheses of anthracycline antibiotics via enantioselective dihydroxylation by osmium tetroxide with a chiral diamine

DOI: 10.1016/S0040-4020(01)80235-0

Source and publish data:

Tetrahedron p. 10807 - 10816 (1993)

Update date:2022-08-03

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Authors:

Nakajima, Makoto

Tomioka, Kiyoshi

Koga, Kenji

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Article abstract of DOI:10.1016/S0040-4020(01)80235-0

Short-step asymmetric syntheses of (+)-7-dehydroxy-4-demethoxydaunomycinone 4 and (-)-9-deacetyl-7-dehydroxy-4-demethoxy-9-hydroxymethyldaunomycinone 5 were accomplished via enantioselective dihydroxylation by osmium tetroxide with chiral diamine 13.

Full text of DOI:10.1016/S0040-4020(01)80235-0

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