Reactivity of the Rhenium(V)-Oxo Complex toward Bis(diphenylphosphino)amine NH(PPh2)2. Synthesis and Crystal Structures

DOI: 10.1039/DT9940000339

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Journal of the Chemical Society, Dalton Transactions p. 339 - 346 (1994)

Update date:2022-08-05

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Authors:

Rossi, Roberto

Marvelli, Lorenza

Marchi, Andrea

Magon, Luciano

Bertolasi, Valerio

Ferretti, Valeria

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Article abstract of DOI:10.1039/DT9940000339

The complexes > 1, > 3 and > 4 were obtained by treatment of with NH(PPh2)2 under different experimental conditions.Their structures were determined by X-ray crystallography.In all complexes the co-ordination is nearly octahedral where a molecule of the ligand binds to rhenium through a phosphorus and oxygen.The Re-O distances, which range from 2.054(3) to 2.071(6) Angstroem indicate the presence of neutral or partially negatively charged oxygens.The Re-Cl bond distances trans to oxygen are strongly related to the oxygen charge and hybridization.

Full text of DOI:10.1039/DT9940000339

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