Reactivity of the Rhenium(V)-Oxo Complex toward Bis(diphenylphosphino)amine NH(PPh2)2. Synthesis and Crystal Structures

DOI: 10.1039/DT9940000339

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 339 - 346 (1994)

Update date:2022-08-05

Topics:

Authors:

Rossi, Roberto

Marvelli, Lorenza

Marchi, Andrea

Magon, Luciano

Bertolasi, Valerio

Ferretti, Valeria

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940000339

The complexes > 1, > 3 and > 4 were obtained by treatment of with NH(PPh2)2 under different experimental conditions.Their structures were determined by X-ray crystallography.In all complexes the co-ordination is nearly octahedral where a molecule of the ligand binds to rhenium through a phosphorus and oxygen.The Re-O distances, which range from 2.054(3) to 2.071(6) Angstroem indicate the presence of neutral or partially negatively charged oxygens.The Re-Cl bond distances trans to oxygen are strongly related to the oxygen charge and hybridization.

Full text of DOI:10.1039/DT9940000339

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:ReCl₃(H₂O){NH(OP(C₆H₅)2)P(C₆H₅)2}*C₂H₅OH

Cas No:154649-07-7

R&D Labs maybe for 154649-07-7

Antimex Chemical Limied

website:http://www.antimex.com

Contact:0086-21-50563169

Address:Room1027,No.Jinyu Road,Pudong
Zhejiang Tianyu Pharmaceutical Co., Ltd.

Contact:+86-576-84177669, 89189665,89189688,84168770

Address:Jiangkou Development Zone, Huangyan, Taizhou City, Zhejiang
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Shanggao Ruiya Fine Chemicals Co., Ltd

Contact:+86-795-2592103

Address:Xingguang Nanlu,Shanggao County Industry Park

Relevant to this article

Nickel-palladium-catalyzed hydroamination/cyclization of sulfur-substituted 1,6-diynes with secondary amines

Doi:10.1016/j.tet.2013.12.049
(2014)
Voltammetric and spectrophotometric study on the complexation of glibenclamide with β-cyclodextrin

Doi:10.1007/s10847-010-9801-9
(2010)
Fluoroalkylation of aromatics: An intramolecular radical cyclization of 4-chloro-1,1,2,2,3,3,4,4-octafluorobutylbenzenes

Doi:10.1016/j.jfluchem.2006.05.013
(2006)
Biomimetic synthesis of ascididemin and derivatives

Doi:10.1055/s-1994-25446
(1994)
Electrochemical Synthesis and Structural Characterization of Bis(triphenylphosphine)copper(I) FLuoroacetates

Doi:10.1039/DT9940000773
(1994)
The first polycondensation through a free radical chain process

Doi:10.1021/ja970165g
(1997)

Article Doi