The Importance of Resonance Stabilization in the Benzylic Solvolysis. Substituent Effects on the Solvolysis of α,α-Diisopropylbenzyl Chlorides

DOI: 10.1016/S0040-4039(00)61418-1

Source and publish data:

Tetrahedron Letters p. 8309 - 8312 (1993)

Update date:2022-07-30

Topics:

Authors:

Fujio, Mizue

Nakata, Kazuhide

Kuwamura, Takashi

Nakamura, Hirotaka

Saeki, Yoshihiro

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)61418-1

The substituent effect on the solvolysis of α,α-diisopropylbenzyl chlorides can be described in terms of ?⁺ value.No significant steric loss of resonance was observed by introducing two bulky isopropyl groups into benzylic reaction center.

Full text of DOI:10.1016/S0040-4039(00)61418-1

Products guided by the article

Product name:4-(1-Chloro-1-isopropyl-2-methyl-propyl)-1,2-dimethyl-benzene

Cas No:155006-13-6

R&D Labs maybe for 155006-13-6

Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China
Chongqing Yawei Fine Chemical Co.,Ltd

Contact:0086-23-62849407

Address:Ziyou village, Nanquan town, Banan district, Chongqing China
Dayang Chem (Hangzhou) Co.,Ltd.

website:http://www.dycnchem.com

Contact:+86-571-88938639

Address:9/F, Unit 2 Changdi Torch Building, 259# WenSan Road, Xihu District, Hangzhou City 310012, P.R.China
NINGBO PANGS CHEM INT’L CO.,LTD.

Contact:+86-574-27666845

Address:FLOOR 21,BUILDING NO.11,XIN TIAN DI,NO.689 SHI JI ROAD,NINGBO CHINA
Shanghai MissYou Chemical Co.,Ltd.

Contact:86-21-58583907

Address:Room606A,?No.800?Shangcheng?Road,?Pudong?New?Area,?Shanghai,?China

Relevant to this article

Heterogeneously copper-catalyzed oxidative synthesis of imidazo[1,2-a]pyridines using 2-aminopyridines and ketones under ligand- and additive-free conditions

Doi:10.1039/c4ra03299c
(2014)
Synthesis of (2R,5S)- and (2S,5S)-2-carboxy-1,4-diaza[4.3.0]bicyclononane as building blocks for the synthesis of new potential HIV protease inhibitors

Doi:10.1016/0957-4166(96)00241-8
(1996)
N-Heterocyclic Carbene Catalyzed (5+1) Annulations Exploiting a Vinyl Dianion Synthon Strategy

Doi:10.1002/anie.201905475
(2019)
Synthesis of vicinal trioxo compounds by dimethyl dioxirane oxidation of 2-diazo-1,3-dioxo derivatives

Doi:10.1080/00397919408012648
(1994)
Synthesis of 4beta-amido and 4beta-sulphonamido analogues of podophyllotoxin as potential antitumour agents.

Doi:10.1016/j.bmc.2003.08.019
(2003)
Synthesis of manool-related labdane diterpenes as platelet aggregation inhibitors

Doi:10.1248/cpb.41.1698
(1993)

Article Doi