The Importance of Resonance Stabilization in the Benzylic Solvolysis. Substituent Effects on the Solvolysis of α,α-Diisopropylbenzyl Chlorides

DOI: 10.1016/S0040-4039(00)61418-1

Source and publish data:

Tetrahedron Letters p. 8309 - 8312 (1993)

Update date:2022-07-30

Topics:

Authors:

Fujio, Mizue

Nakata, Kazuhide

Kuwamura, Takashi

Nakamura, Hirotaka

Saeki, Yoshihiro

et al. et al.

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Article abstract of DOI:10.1016/S0040-4039(00)61418-1

The substituent effect on the solvolysis of α,α-diisopropylbenzyl chlorides can be described in terms of ?⁺ value.No significant steric loss of resonance was observed by introducing two bulky isopropyl groups into benzylic reaction center.

Full text of DOI:10.1016/S0040-4039(00)61418-1

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