Synthetic approaches to homotropanes and homotrop-7-enes using intramolecular displacement and amidomercuration strategies

Article abstract of DOI:10.1016/S0040-4020(01)80257-X

1,4-Functionalisation of cycloocta-1,3-diene using a nitroso-cycloaddition strategy is followed by intramolecular displacement by nitrogen to yield the 9-methyl-9-azabicyclo[4.2.1)nonane (homotropane) and -non-7-ene (homotrop-7-ene) systems and N-benzyl d