Bound and Non-bound Tetracyanoethylene Radical Anion (TCNE radical anion) in Copper(I) Triphenylphosphine Complexes. The Crystal Structures of Cu(TCNE)(PPh3)3, n and

DOI: 10.1039/c39940000541

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 541 - 544 (1994)

Update date:2022-07-30

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Authors:

Olmstead, Marilyn M.

Speier, Gabor

Szabo, Lajos

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Article abstract of DOI:10.1039/c39940000541

The reaction of the copper(II) complex n with triphenylphosphine yields three different modes of incorporation of TCNE radical anion into the products Cu(TCNE)(PPh3)3 1, <-(CN)Cu(PPh3)2(TCNE)Cu(PPh3)2->n 2 and <(PPh3)3Cu(CN)Cu(PPh3)3> 3.In 1, the TCNE radical anion is N-bound; in 2, trans-N-bound TCNE radical anion bridges alternate with CN bridges to produce a polymeric structure, and in 3 the TCNE radical anion is un-coordinated.

Full text of DOI:10.1039/c39940000541

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