Bound and Non-bound Tetracyanoethylene Radical Anion (TCNE radical anion) in Copper(I) Triphenylphosphine Complexes. The Crystal Structures of Cu(TCNE)(PPh3)3, n and

DOI: 10.1039/c39940000541

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 541 - 544 (1994)

Update date:2022-07-30

Topics:

Authors:

Olmstead, Marilyn M.

Speier, Gabor

Szabo, Lajos

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940000541

The reaction of the copper(II) complex n with triphenylphosphine yields three different modes of incorporation of TCNE radical anion into the products Cu(TCNE)(PPh3)3 1, <-(CN)Cu(PPh3)2(TCNE)Cu(PPh3)2->n 2 and <(PPh3)3Cu(CN)Cu(PPh3)3> 3.In 1, the TCNE radical anion is N-bound; in 2, trans-N-bound TCNE radical anion bridges alternate with CN bridges to produce a polymeric structure, and in 3 the TCNE radical anion is un-coordinated.

Full text of DOI:10.1039/c39940000541

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Cu(tetracyanoethylene)(PPh₃)3

Cas No:155452-19-0

R&D Labs maybe for 155452-19-0

SICHUAN ZHONGBANG NEW MATERIAL CO., LTD

website:http://www.zhongbangst.com

Contact:86-830-2585019

Address:sichuan,china
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Jiaxing Carry Bio-Chem Technology Co.,Ltd

website:http://www.carrybiotech.com

Contact:0573-82788958

Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China
Shanghai Bosman Industrial Co., Ltd

Contact:86-21-63065878-8006

Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
Huayang chemical Co., LTD

Contact:+86-18653358619

Address:zibo

Relevant to this article

NMR studies on [2+3] cycloaddition of nitrile oxides to cyclohexene derivatives

Doi:10.1016/j.molstruc.2013.12.035
(2014)
Fungal metabolites. IX. Synthesis of a membrane-modifying peptide, hypelcin A-III, from Hypocrea peltata

Doi:10.1248/cpb.41.1955
(1993)
Thermolysis of 3,3-bis(phenylmethyl)-1,2-dioxetane: Radical-induced formation of the unusual decomposition product 3-phenyl-1-(phenylmethoxy)-2-propanone

Doi:10.1021/ja00092a019
(1994)
Convenient selective synthesis of pyrano[2,3-d]pyrimidines

Doi:10.1007/s11172-008-0308-0
(2008)
Synthesis of Some Bridgehead-Bridgehead-Disubstituted Bicyclo<1.1.1>pentanes

Doi:10.1021/jo00090a015
(1994)
The Total Synthesis of Swinholide A. Part 3: A Stereocontrolled Synthesis of (-)-Pre-Swinholide A.

Doi:10.1016/0040-4020(95)00548-M
(1995)

Article Doi