Journal of Organic Chemistry p. 2986 - 2996 (1994)
Update date:2022-07-30
Topics: Purification and characterization Bridgehead Substitution
Della, Ernest W.
Taylor, Dennis K.
The synthesis of a wide variety of 1,3-disubstituted bicyclo<1.1.1>pentanes is described, with particular emphasis on the generation of a series of 3-X-substituted bicyclo<1.1.1>pentyl bromides required for solvolytic studies.Functional group manipulation at the bridgehead was readily accomplished in the majority of cases by radical processes; in some instances, transformations were effected via carbanionic-type intermediates.
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