Tetrahedron Asymmetry p. 2211 - 2218 (1993)
Update date:2022-08-04
Topics:
Poppe, Laszlo
Novak, Lajos
Kajtar-Peredy, Maria
Szantay, Csaba
Enantiomer selective hydrolysis of racemic 1,2-diol diacetates (rac-2a-h) was investigated by using the inexpensive commercial porcine pancreatic lipase.The hydrolysis proceeds with variable regioselectivity but with moderate to good enantioselectivity yielding a mixture of isomeric monoacetates (3a-h and 4a-h) and unchanged diacetate enantiomers (2a-h).Evidence was found that both monoacetates (3a-h and 4a-h) are formed with the same sense of enantiomer selectivity.
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