Effect of the ligand and metal on the pKa values of the dihydrogen ligand in the series of complexes [M(H2)H(L)2]+, M = Fe, Ru, Os, containing isosteric ditertiaryphosphine ligands, L

DOI: 10.1021/ja00087a024

Source and publish data:

Journal of the American Chemical Society p. 3375 - 3388 (1994)

Update date:2022-07-30

Topics: Complexes Fe

Authors:

Cappellani, E. Paul

Drouin, Samantha D.

Jia, Guochen

Maltby, Patricia A.

Morris, Robert H.

Schweitzer, Caroline T.

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Article abstract of DOI:10.1021/ja00087a024

The new dihydrogen complexes trans-[MH(H₂)L₂] BF₄, L = P(C₆H₄-4-R)₂CH₂CH ₂P(C₆H₄-4-R)₂ R = CF₃, M = Fe, Ru, and Os, R = CH<

Full text of DOI:10.1021/ja00087a024

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Product name:RuCl₂((CH₃OC₆H₄)2PC₂H₄P(C₆H₄OCH₃)2)2

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