Journal of Organometallic Chemistry p. 169 - 180 (1994)
Update date:2022-08-03
Topics:
Blaschette, Armand
Lange, Ilona
Krahl, Juergen
Koch, Dietrich
Jones, Peter G.
By reacting R3SnCl with AgN(SO2R)2 and/or R3SnOH with HN(SO2R)2, the following compounds were obtained: R3SnN(SO2Me)2, where R = Et (3), nBu, Ph (5) or cHex (6); Me3SnN(SO2C6H4Cl-p)2; Me3SnZ and Me3SnZ*H2O (Z = anion of benzene-1,2-disulfonimide).With dimethyl sulfoxide, 3 gives the 1/2 complex Et3SnN(SO2Me)2*2DMSO.An improved method of preparation is described for the structurally known aqua complex
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