A Stereoselective Synthesis of (-)-Isoiridomyrmecin. Application of the Asymmetric Aza-Claisen Rearrangement

DOI: 10.1246/cl.1994.543

Source and publish data:

Chemistry Letters p. 543 - 546 (1994)

Update date:2022-08-03

Topics:

Authors:

Tsunoda, Tetsuto

Tatsuki, Shinji

Kataoka, Kazuko

Ito, Sho

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1994.543

(-)-Isoiridomyrmecin was synthesized stereoselectively in 6 steps starting from 1-hydroxymethyl-5-methylcyclopentene and utilizing the asymmetric aza-Claisen rearrangement as a key step.

Full text of DOI:10.1246/cl.1994.543

Products guided by the article

Product name:4-Methyl-N-((S)-5-methyl-cyclopent-1-enylmethyl)-N-((S)-1-phenyl-ethyl)-benzenesulfonamide

Cas No:155694-27-2

R&D Labs maybe for 155694-27-2

Shenzhen Hongyuan Import & Export Co., Ltd.

Contact:0755-26407171

Address:Shenzhen Hongyuan Chemical New Materials Technology Co., Ltd.
ShangHai Soyoung Biotechnology Inc

website:http://www.soyoungbio.com

Contact:+86-21-69893009

Address:shanghai
Nanjing HuiBaiShi Biotechnology Co.,Ltd.

Contact:+86 (25)58745219

Address:No.606 Ningliu Road,LiuHe District.
Golden Union Agrochemical Import and Export Co., Ltd.

Contact:86-755-23910527

Address:Room 1106, Tower 3A, Excellence Century Center, Futian District, Shenzhen, China
Xi'an Costrong Pharmaceutical Co., Ltd.

Contact:029- 68576496

Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China

Relevant to this article

Structural Studies on Bioactive Compounds. 23. Synthesis of Polyhydroxylated 2-Phenylbenzothiazoles and a Comparison of Their Cytotoxicities and Pharmacological Properties with Genistein and Quercetin

Doi:10.1021/jm00037a020
(1994)
4',6'-Methano carbocyclic thymidine: A conformationally constrained building block for oligonucleotides

Doi:10.1016/0040-4039(94)85212-X
(1994)
3H-azepines and related systems. Part 5. Photo-induced ring expansions of o-azidobenzonitriles to 3-cyano- and 7-cyano-3H-azepin-2(1H)-ones

Doi:10.1016/S0040-4020(01)80706-7
(1994)
Total synthesis of a modified ganglioside, de-N-acetyl GM₂

Doi:10.1016/0008-6215(94)00155-3
(1994)
Synthesis and antimicrobial activities of some 6-methyl-3-thioxo-2,3- dihydro-1,2,4-triazine derivatives

Doi:10.1080/10426507.2012.755972
(2014)
Rhodium(III)-catalyzed ortho -alkenylation through C-H bond cleavage directed by sulfoxide groups

Doi:10.1021/ol5000605
(2014)

Article Doi