A Stereoselective Synthesis of (-)-Isoiridomyrmecin. Application of the Asymmetric Aza-Claisen Rearrangement

DOI: 10.1246/cl.1994.543

Source and publish data:

Chemistry Letters p. 543 - 546 (1994)

Update date:2022-08-03

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Authors:

Tsunoda, Tetsuto

Tatsuki, Shinji

Kataoka, Kazuko

Ito, Sho

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Article abstract of DOI:10.1246/cl.1994.543

(-)-Isoiridomyrmecin was synthesized stereoselectively in 6 steps starting from 1-hydroxymethyl-5-methylcyclopentene and utilizing the asymmetric aza-Claisen rearrangement as a key step.

Full text of DOI:10.1246/cl.1994.543

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