Benzyl Methyl (S)-2-(p-Tolylsulfinyl)maleate: An Efficient Dienophile for the Enantioselective Synthesis of Cyclohexadienes

DOI: 10.1021/jo00064a005

Source and publish data:

Journal of Organic Chemistry p. 3231 - 3232 (1993)

Update date:2022-08-04

Topics:

Authors:

Alonso, Ines

Carretero, Juan C.

Ruano, Jose L. Garcia

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Article abstract of DOI:10.1021/jo00064a005

The new dienophile, benzyl methyl (S)-2-(p-tolylsulfinyl)maleate, readily prepared in two steps from benzyl acetate, reacts with a wide variety of 1,3-dienes, under catalysis by TiCl4, in a very regioselective and stereoselective manner to give optically

Full text of DOI:10.1021/jo00064a005

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