First Example of Reversal of Normal Stereoselectivity in the Intramolecular Pauson-Khand Reaction

DOI: 10.1016/0040-4039(94)88010-7

Source and publish data:

Tetrahedron Letters p. 1153 - 1156 (1994)

Update date:2022-08-05

Topics:

Authors:

Casalnuovo, Joseph A.

Scott, Robert W.

Harwood, Eric A.

Schore, Neil E.

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Article abstract of DOI:10.1016/0040-4039(94)88010-7

Stereoselectivity favoring exo substituent orientation in the intramolecular Pauson-Khand reaction of 3-methyl-4-hydroxy-1,6-heptenynes to form bicyclo<3.3.0>octenones is affected by the relative stereochemistry at C3 and C4.Cycloaddition of one stereoiso

Full text of DOI:10.1016/0040-4039(94)88010-7

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