A short asymmetric synthesis of (+)-nonactic acid and (-)-8-epi-nonactic acid induced by a chiral sulfoxide group

DOI: 10.1021/jo00093a022

Source and publish data:

Journal of Organic Chemistry p. 3898 - 3901 (1994)

Update date:2022-08-02

Topics:

Authors:

Solladie

Dominguez

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Article abstract of DOI:10.1021/jo00093a022

A short enantioselective synthesis of (+)-(2S,3S,6R,8R)-nonactic acid and (-)-(2R,3R,6S,8R)-epinonactic acid is described. The key step was the stepwise stereoselective reduction of the triketo sulfoxide B without any protective group on the different carbonyls.

Full text of DOI:10.1021/jo00093a022

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