Tetrahedron Letters p. 4561 - 4564 (1984)
Update date:2022-08-05
Topics:
Ohkata, Katsuo
Ohyama, Yoshihiko
Watanabe, Yuko
Akiba, Kin-ya
Substituents at 5-position of 5-amino-3-methyl- and 3-p-chlorophenyl-5-methylisothiazoles (7 and 8) were silylated and then lithiated to couple with aromatic nitriles in order to afford the adducts (4 and 5) via 1,3-silyl group shift.Desilylation of 5 wit
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