RING-TRANSFORMATION EQUILIBRIUM WITH PARTICIPATION OF ?-BONDED S(IV) IN AN ISOTHIAZOLE SYSTEM. SYNTHESIS OF NON-RING-TRANSFORMED 5-(2-AMINOVINYL)ISOTHIAZOLE DERIVATIVE VIA 1,3-SILYL GROUP SHIFT

DOI: 10.1016/S0040-4039(01)81493-3

Source and publish data:

Tetrahedron Letters p. 4561 - 4564 (1984)

Update date:2022-08-05

Topics:

Authors:

Ohkata, Katsuo

Ohyama, Yoshihiko

Watanabe, Yuko

Akiba, Kin-ya

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81493-3

Substituents at 5-position of 5-amino-3-methyl- and 3-p-chlorophenyl-5-methylisothiazoles (7 and 8) were silylated and then lithiated to couple with aromatic nitriles in order to afford the adducts (4 and 5) via 1,3-silyl group shift.Desilylation of 5 wit

Full text of DOI:10.1016/S0040-4039(01)81493-3

Products guided by the article

Product name:3-phenyl-5-(tert-butyldimethylsilyl)methylisoxazole

Cas No:156088-10-7

R&D Labs maybe for 156088-10-7

Jiangxi Global Natural Spice Co., Ltd.

website:https://www.jxhqxl.com/

Contact:+86-796-8106598

Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Jinan Hongfangde Pharmatech Co.,Ltd

Contact:86-531-88870908

Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China
Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China

Relevant to this article

Nouvelle cyclopentannelation regioselective par une sequence tandem: Ouverture electrophile/cycloaddition [3+2] entre cetones methylenecyclopropaniques et l'allyltrimethylsilane

Doi:10.1016/S0040-4020(98)00335-4
(1998)
Carbon-Carbon Bond-Forming Reaction through a η⁵-Pentadienylchromium Complex

Doi:10.1021/jo00083a007
(1994)
Studies Directed toward the Synthesis of (+)-Sesbanimide A: Construction of the AB-Ring System (A Formal Total Synthesis)

Doi:10.1021/jo00090a025
(1994)
Multiple C-H bond cleavage of the alkyl group in (2,6-Dialkylphenoxo) ruthenium(II) complexes

Doi:10.1021/om5000248
(2014)
Synthesis of di- and tri-saccharides with intramolecular NH-glycosidic linkages: Molecules with flexible and rigid glycosidic bonds for conformational studies

Doi:10.1016/0008-6215(94)90013-2
(1994)
New zirconocenes with 4,5,6,7-tetrahydroindene ligands. Synthesis and catalytic activity in the polymerization of ethylene and copolymerization of ethylene with hex-1-ene

Doi:10.1007/s11172-016-1485-x
(2016)

Article Doi