Mono- and Bi-dentate Phosphaalkene Ligands: Structures of their Copper(I) Chloride Complexes

DOI: 10.1039/DT9940001685

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1685 - 1688 (1994)

Update date:2022-07-29

Topics:

Authors:

Jouaiti, Abdelaziz

Geoffroy, Michel

Bernardinelli, Gerald

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940001685

While the reaction of the monophosphaalkene <(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl>benzene (L²) with copper(I) chloride led to a dimeric complex 22(NCMe)2> 1, use of the diphosphaalkene 1,3-bis<(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl>benzene (L¹) gave rise to a tetrameric complex 12>*3EtOH 2.The crystal structures of the complexes have been determined and indicate that 1 is a centrosymmetric dimer with tetrahedrally co-ordinated copper(I) centres, whereas 2 adopts a 'cubane-like' structure with pairs of copper atoms bridged by different L¹ units.

Full text of DOI:10.1039/DT9940001685

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Cu₂Cl₂(CH₃CN)2(P(C₆H₂(C(CH₃)3)3)CHC₆H₅)2

Cas No:156754-78-8

R&D Labs maybe for 156754-78-8

HANGZHOU PANYU CHEMICAL CO.,LIMITED

Contact:+86-571-86578491

Address:Rm 605, NO.1870 Binsheng Road,Binjiang Dist, Hangzhou, China
qingdao goldenchem imp and exp co.,ltd.

Contact:532-55579246

Address:no.62 ,haier road laoshan distirct
Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China
Antimex Chemical Limied

website:http://www.antimex.com

Contact:0086-21-50563169

Address:Room1027,No.Jinyu Road,Pudong
Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City

Relevant to this article

Synthesis, characterization, and fiber-optic infrared reflectance spectroelectrochemical studies of some dinitrosyl iron diphosphine complexes Fe(NO)₂L₂ (L = P(C₆H₄X)₃)

Doi:10.1016/j.jorganchem.2013.12.040
(2014)
Syntheses and crystal and molecular structures of hexaaquaruthenium(II) p-toluenesulfonate and hexaaquaruthenium(III) p-toluenesulfonate, [Ru(H₂O)₆](C₇H₇SO₃) ₂ and [Ru(H₂O)₆](C₇H₇SO₃) ₃·3H₂O

Doi:10.1021/ic00141a016
(1982)
Vicinal difunctionalization of alkenes: Chlorotrifluoromethylation with CF₃SO₂Cl by photoredox catalysis

Doi:10.1021/ol403716t
(2014)
Synthesis and evaluation of neuroprotective 4-O-substituted chrysotoxine derivatives as potential multifunctional agents for the treatment of Alzheimer's disease

Doi:10.1039/c5ra21313d
(2016)
Bis(triphenyl-λ⁵-phosphanylidene)ammonium fluoride: A reactive fluoride source to access the hypervalent silicates [Me _nSiF_5-n]^- (n = 0-3)

Doi:10.1039/c3dt52617h
(2014)
Methyl ketone oxime esters as nucleophilic coupling partners in Pd-catalyzed C-H alkylation and application in the synthesis of isoquinolines

Doi:10.1021/jo5010586
(2014)

Article Doi