Mono- and Bi-dentate Phosphaalkene Ligands: Structures of their Copper(I) Chloride Complexes

DOI: 10.1039/DT9940001685

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1685 - 1688 (1994)

Update date:2022-07-29

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Authors:

Jouaiti, Abdelaziz

Geoffroy, Michel

Bernardinelli, Gerald

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Article abstract of DOI:10.1039/DT9940001685

While the reaction of the monophosphaalkene <(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl>benzene (L²) with copper(I) chloride led to a dimeric complex 22(NCMe)2> 1, use of the diphosphaalkene 1,3-bis<(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl>benzene (L¹) gave rise to a tetrameric complex 12>*3EtOH 2.The crystal structures of the complexes have been determined and indicate that 1 is a centrosymmetric dimer with tetrahedrally co-ordinated copper(I) centres, whereas 2 adopts a 'cubane-like' structure with pairs of copper atoms bridged by different L¹ units.

Full text of DOI:10.1039/DT9940001685

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