Journal of Organic Chemistry p. 4576 - 4595 (1994)
Update date:2022-08-05
Topics: Stereoselective synthesis Nitroalkene <4 + 2> Cycloadditions 2-(Acyloxy)vinyl Ethers 3-Hydroxy-4-substituted-pyrrolidines
Denmark, Scott E.
Schnute, Mark E.
2-(Acyloxy)vinyl ethers undergo regioselective <4 + 2> cycloadditions with nitroalkenes (promoted by SnCl4) to afford substituted 5-acetoxy nitronates in good yields (68-91percent).Endo/exo selectivity in cycloadditions has been found to be dependent on t
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