Journal of the Chemical Society, Dalton Transactions p. 1401 - 1408 (1994)
Update date:2022-09-26
Topics:
Baker, Paul K.
Harris, Sharman D.
Durrant, Marcus C.
Hughes, David L.
Richards, Raymond L.
Reaction of a slight excess of RS(CH2)2SR (R = Ph, 4-MeC6H4 or 4-FC6H4) in CH2Cl2 at room temperature gave a carbonyl ligand in the unique capping position.Low-temperature 13C NMR studies on the tungsten complexes suggest that their structures in solution are similar to the solid-state structure found.Reaction of a capped octahedron with a carbonyl ligand in the unique capping position.
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