Reaction of Phenyldiazomethane with 1,3-Thiazole-5(4H)-thiones: Base-Catalyzed Ring Opening of the Primary Adduct

DOI: 10.1002/hlca.19940770421

Source and publish data:

Helvetica Chimica Acta p. 1076 - 1086 (1994)

Update date:2022-08-03

Topics:

Authors:

Petit, Mireille

Linden, Anthony

Mloston, Grzegorz

Heimgartner, Heinz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19940770421

Reaction of 1,3-thiazole-5(4H)-thiones 1 and phenyldiazomethane (2a) in toluene at room temperature yields the thiiranes trans- and cis-1,4-dithia-6-azaspiro<2.4>hept-5-enes (trans-and cis-4; Scheme 2).With Ph3P in THF at 70 deg C, these thiiranes are tra

Full text of DOI:10.1002/hlca.19940770421

Products guided by the article

Product name:N-<1-Methyl-1-(5-phenyl-1,3,4-thiadiazol-2-yl)ethyl>-isothiocyanat

Cas No:156948-14-0

R&D Labs maybe for 156948-14-0

Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
Luna Chemicals Co.,Ltd.

Contact:+86-570-4336358

Address:No.87 Building,Tianqian,Sidu Town
TIANJIN FESTO CHEMICAL CO.,LTD(expird)

Contact:86-22-25814570

Address:No.12th,5th Ave.,TEDA,Tianjin,China
Yantai Derun Liquid Crystal Materials Co. Ltd.

website:http://www.ytderun.com

Contact:86-535-6300169

Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road

Relevant to this article

Improved Large-Scale Synthesis of Bosentan Monohydrate

Doi:10.1080/00304948.2016.1234826
(2016)
A General Mechanistic Scheme for Intramolecular Electrochemical Hydrocyclizations. Mechanism of the Electroreductive Cyclization of ω-Keto-α,β-unsaturated Esters

Doi:10.1021/jo00096a054
(1994)
The synthesis of β-heteroarylamino-α,β-dehydro-α-amino acid derivatives via thiazolones

Doi:10.1002/jhet.5570310133
(1994)
Iodine-Catalyzed Facile Approach to Sulfones Employing TosMIC as a Sulfonylating Agent

Doi:10.1021/acs.orglett.7b00896
(2017)
Carbohydrate haptens: 4-nitrophenyl 2-acetamido-2-deoxy-β-D-glucopyranosyl-(1 -> 6)-α-D-mannopyranosyl-(1 -> 6)-β-D-mannopyranoside and a related trisaccharide

Doi:10.1016/0008-6215(94)84063-6
(1994)
Three new pseudohalide bridged dinuclear Zn(II), Cd(II) complexes of pyrimidine derived Schiff base ligands: Synthesis, crystal structures and fluorescence studies

Doi:10.1016/j.poly.2011.11.031
(2012)

Article Doi