Gold(I)-catalyzed asymmetric aldol reactions of fluorinated benzaldehydes with an α-isocyanoacetamide

DOI: 10.1016/0957-4166(94)80059-6

Source and publish data:

Tetrahedron Asymmetry p. 1091 - 1094 (1994)

Update date:2022-08-05

Topics: Asymmetric aldol reaction Gold(I) Catalyst Gold(I)-Catalyzed Aldol Reactions Text format Experimental

Authors:

Soloshonok

Hayashi Hayashi

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Article abstract of DOI:10.1016/0957-4166(94)80059-6

The use of N,N-dimethyl-α-isocyanoacetamide instead of methyl α-isocyanoacetate in the gold(I)-catalyzed asymmetric aldol reactions with polyfluorinated benzaldehydes was found to improve both diastereo- and enantioselectivity in the formation of trans-ox

Full text of DOI:10.1016/0957-4166(94)80059-6

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