Organometallic materials for non-linear optics. Second harmonic generation by (aryldiazovinylidene)ruthenium complexes; X-ray structure of *CH2Cl2

DOI: 10.1016/0022-328X(94)88125-1

Source and publish data:

Journal of Organometallic Chemistry p. 193 - 200 (1994)

Update date:2022-08-04

Topics:

Authors:

Whittall, Ian R.

Cifuentes, Marie P.

Costigan, Marion J.

Humphrey, Mark G.

Goh, Seng C.

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(94)88125-1

A series of (aryldiazovinylidene)ruthenium complex salts of general formula has been synthesized.The Kurtz method was used to investigate their effectiveness in second harmonic generation, and revealed efficiencies up to that of a urea reference standard.An X-ray structural study of the complex exhibiting the strongest response, *CH2Cl2 revealed that the material packs centrosymmetrically, suggesting that the observed moderate bulk χ⁽²⁾ responses arise from large molecular β responses and some crystal mispacking.Key words: Ruthenium; Second harmonic generation; Solvochromatic properties; Cyclopentadienyl

Full text of DOI:10.1016/0022-328X(94)88125-1

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