Organometallic materials for non-linear optics. Second harmonic generation by (aryldiazovinylidene)ruthenium complexes; X-ray structure of *CH2Cl2

DOI: 10.1016/0022-328X(94)88125-1

Source and publish data:

Journal of Organometallic Chemistry p. 193 - 200 (1994)

Update date:2022-08-04

Topics:

Authors:

Whittall, Ian R.

Cifuentes, Marie P.

Costigan, Marion J.

Humphrey, Mark G.

Goh, Seng C.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)88125-1

A series of (aryldiazovinylidene)ruthenium complex salts of general formula has been synthesized.The Kurtz method was used to investigate their effectiveness in second harmonic generation, and revealed efficiencies up to that of a urea reference standard.An X-ray structural study of the complex exhibiting the strongest response, *CH2Cl2 revealed that the material packs centrosymmetrically, suggesting that the observed moderate bulk χ⁽²⁾ responses arise from large molecular β responses and some crystal mispacking.Key words: Ruthenium; Second harmonic generation; Solvochromatic properties; Cyclopentadienyl

Full text of DOI:10.1016/0022-328X(94)88125-1

Products guided by the article

Product name:[Ru(CC(C₆H₅)NNC₆H₅)(P(C₆H₅)3)2(C₅H₅)]⁽¹⁺⁾*NO₃^(1-)=[Ru(CC(C₆H₅)NNC₆H₅)(P(C₆H₅)3)2(C₅H₅)][NO₃]

Cas No:157183-95-4

R&D Labs maybe for 157183-95-4

Tianjin Te-An Chemtech Co., Ltd.(expird)

Contact:+86-22-65378638

Address:A5-8, No.80 Haiyun Street, TEDA
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD

Contact:+86-571-88932183

Address:Hangzhou
Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
Henan Yellow River New Material Technology Co.Ltd.

website:http://www.yellowriverchem.com

Contact:0086-373-7278760

Address:Chengguan Town, Yuanyang County
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C

Relevant to this article

Synthesis and cytotoxic effect of pseudodiosgenyl saponins with thio-ring F

Doi:10.1016/j.bmcl.2014.01.055
(2014)
Synthetic Applications of 2-(1,3-Dithian-2-yl)indoles. IV. New Synthesis of the Tetracyclic ABED Ring System of Strychnos Alkaloids

Doi:10.1016/S0040-4020(01)89689-7
(1994)
Flexible and stereoselective construction of polypropionate chains from enantiomerically pure γ-hydroxy-α,β-unsaturated sulfones

Doi:10.1016/S0040-4020(01)90483-1
(1994)
Development of new LXR modulators that regulate LXR target genes and reduce lipogenesis in human cell models

Doi:10.1016/j.ejmech.2014.01.003
(2014)
Synthesis and structure of the phosphinophosphide niobocene complex Cp₂Nb(PPh₂)(PHPh₂)

Doi:10.1016/S0277-5387(98)00408-2
(1999)
Organic syntheses via Transition metal complexes. 72. (2-(acyloxy)ethenyl)carbene complexes by Michael addition of carboxylic acids to alkynylcarbene complexes (M = Cr, W). (2-(acyloxy)ethenyl)ketene imines by ligand disengagement with isocyanide

Doi:10.1021/om00021a025
(1994)

Article Doi