Terpenoid Chirons: Preparation and Transformations of 2-Hydroxy-1,1,4a(R),6-Tetramethyl-Trans-Δ5,6-Octalin

DOI: 10.1016/S0040-4039(00)73036-X

Source and publish data:

Tetrahedron Letters p. 2013 - 2016 (1994)

Update date:2022-08-05

Topics:

Authors:

Falck, J. R.

Manna, Sukumar

Chandrasekhar, S.

Alcaraz, L.

Mioskowski, C.

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Article abstract of DOI:10.1016/S0040-4039(00)73036-X

Octalins 4 and 5 are prepared conveniently in 3 steps from commercial 18β-glycyrrhetinic acid and converted to a variety of functionalized trans AB ring chirons.KEYWORDS: thermolysis, steroid, octahydronaphthalene, retro-Diels-Alder, glycyrrhetinic acid

Full text of DOI:10.1016/S0040-4039(00)73036-X

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Product name:tert-Butyl-diphenyl-((2S,4aR,8aR)-1,1,4a,6-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-yloxy)-silane

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