Synthesis and ring-opening reactions of cationic ruthenium biaryl thionolactone complexes

DOI: 10.1016/0022-328X(94)80213-0

Source and publish data:

Journal of Organometallic Chemistry p. 275 - 284 (1994)

Update date:2022-08-04

Topics:

Authors:

Bringmann, G.

Schoener, B.

Schupp, O.

Schenk, W.A.

Reuther, I.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)80213-0

The preparations of novel thionolactone-bridged configuratively labile biaryls and their ⁺-complexes are described.The dynamics of helimerization of these complexes and their reactivity towards nucleophiles have been investigated.Hydride transfer reagents lead to a cleavage ofthe thionolactone bridge to give the corresponding thiolate complexes, apparently via intermediate exothiolactolate ruthenium complexes.A similar lactolate analog is formed upon addition of a mild S-nucleophile.Key words: Ruthenium; Crystal structure; Thionolactone; Ring opening; Fluxionality

Full text of DOI:10.1016/0022-328X(94)80213-0

Products guided by the article

Product name:C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)]BF₄

Cas No:157620-29-6

R&D Labs maybe for 157620-29-6

Chengdu Aslee Biopharmaceuticals, Inc

Contact:18608018419

Address:Chengdu Aslee Biopharmaceuticals, Inc
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China
Changzhou Ruiping Chemical Co., Ltd

website:http://www.wishchem.com

Contact:+86-519-82324280

Address:No.288-1 Huacheng Road, Jintan
Anhui Sunsing Chemicals Co.,Ltd

website:http://www.sunsingchem.com

Contact:0086-566-2023179

Address:Jin An industry park, Chizhou economic technical development zone, Anhui
Henan Harvest Chem Co., Ltd

Contact:+86-371-86058576

Address:NO.32, Jingsan Road, Zhengzhou, China

Relevant to this article

Novel Asp³²-replacement tetrapeptide analogues as potent and selective CCK-A agonists

Doi:10.1021/jm00037a005
(1994)
DPPA-promoted decarbonylation of a N-Cbz-(D,L)-pipecolinic acid derivative: An easy entry to [4.5]spirolactams and [4.5]spirolactones. Total synthesis of (±)-δ-coniceine

Doi:10.1016/S0040-4039(00)73161-3
(1994)
Doi:10.1016/0022-1902(80)80033-9
(1980)
Formal total synthesis of FK506. Concise construction of the C(10)-C(34) segment via an effective coupling tactic

Doi:10.1016/S0040-4039(00)73331-4
(1994)
Toward new classes of potent antibiotics: Synthesis and antimicrobial activity of novel metallosaldach-imidazolium salts

Doi:10.1016/j.ejmech.2013.09.029
(2014)
Regioselective Ylide Formation on Acetal-Functionalized Trialkyl Phosphonium Salts: Extending the Scope of Carbonyl Homologation

Doi:10.1055/s-0036-1588551
(2017)

Article Doi