Synthesis and ring-opening reactions of cationic ruthenium biaryl thionolactone complexes

DOI: 10.1016/0022-328X(94)80213-0

Source and publish data:

Journal of Organometallic Chemistry p. 275 - 284 (1994)

Update date:2022-08-04

Topics:

Authors:

Bringmann, G.

Schoener, B.

Schupp, O.

Schenk, W.A.

Reuther, I.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)80213-0

The preparations of novel thionolactone-bridged configuratively labile biaryls and their ⁺-complexes are described.The dynamics of helimerization of these complexes and their reactivity towards nucleophiles have been investigated.Hydride transfer reagents lead to a cleavage ofthe thionolactone bridge to give the corresponding thiolate complexes, apparently via intermediate exothiolactolate ruthenium complexes.A similar lactolate analog is formed upon addition of a mild S-nucleophile.Key words: Ruthenium; Crystal structure; Thionolactone; Ring opening; Fluxionality

Full text of DOI:10.1016/0022-328X(94)80213-0

Products guided by the article

Product name:C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)]BF₄

Cas No:157620-29-6

R&D Labs maybe for 157620-29-6

China Synchem Technology Co.,Ltd

website:http://www.cnsynchem.com

Contact:+86-0552-4929311

Address:No.217 Daqing Road
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
Wuxi Innopal International Trade CO.,LTD

Contact:+86-510-80711901-8003

Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China
Chengdu Pukang Biotechnology Co., Ltd

website:http://www.pu-kang.com

Contact:86-028-63976226

Address:No. 868 Xiwang Road,Xinjin county,Chengdu city, China
Molobelamltrading

Contact:27-792-602929

Address:SIDNEY MUFAMADI STREET 009949 X44 0700 POLOKWANE,LIMPOPO

Relevant to this article

Novel Asp³²-replacement tetrapeptide analogues as potent and selective CCK-A agonists

Doi:10.1021/jm00037a005
(1994)
DPPA-promoted decarbonylation of a N-Cbz-(D,L)-pipecolinic acid derivative: An easy entry to [4.5]spirolactams and [4.5]spirolactones. Total synthesis of (±)-δ-coniceine

Doi:10.1016/S0040-4039(00)73161-3
(1994)
Doi:10.1016/0022-1902(80)80033-9
(1980)
Formal total synthesis of FK506. Concise construction of the C(10)-C(34) segment via an effective coupling tactic

Doi:10.1016/S0040-4039(00)73331-4
(1994)
Toward new classes of potent antibiotics: Synthesis and antimicrobial activity of novel metallosaldach-imidazolium salts

Doi:10.1016/j.ejmech.2013.09.029
(2014)
Regioselective Ylide Formation on Acetal-Functionalized Trialkyl Phosphonium Salts: Extending the Scope of Carbonyl Homologation

Doi:10.1055/s-0036-1588551
(2017)

Article Doi