Synthesis and ring-opening reactions of cationic ruthenium biaryl thionolactone complexes

DOI: 10.1016/0022-328X(94)80213-0

Source and publish data:

Journal of Organometallic Chemistry p. 275 - 284 (1994)

Update date:2022-08-04

Topics:

Authors:

Bringmann, G.

Schoener, B.

Schupp, O.

Schenk, W.A.

Reuther, I.

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(94)80213-0

The preparations of novel thionolactone-bridged configuratively labile biaryls and their ⁺-complexes are described.The dynamics of helimerization of these complexes and their reactivity towards nucleophiles have been investigated.Hydride transfer reagents lead to a cleavage ofthe thionolactone bridge to give the corresponding thiolate complexes, apparently via intermediate exothiolactolate ruthenium complexes.A similar lactolate analog is formed upon addition of a mild S-nucleophile.Key words: Ruthenium; Crystal structure; Thionolactone; Ring opening; Fluxionality

Full text of DOI:10.1016/0022-328X(94)80213-0

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Product name:C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)]BF₄

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