
Tetrahedron Asymmetry p. 717 - 722 (1994)
Update date:2022-08-05
Topics:
Savignac
Durand
Genet
MeBmt 1 was prepared in four steps from the optically pure (2Z, 4R) 4-methyloct-6-yn-2-en-1-ol 8, Z allylic alcohol containing an alkynyl group at the γ position. The two stereogenic centers C-2 and C-3 in the product were controlled using Sharpless' epoxidation and subsequent ring opening at C-2 of the epoxy acid 10 with methylamine.
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Doi:10.1021/jacs.0c09083
(2020)Doi:10.1021/acscatal.5b02766
(2016)Doi:10.1016/j.tet.2014.02.038
(2014)Doi:10.1016/j.tetlet.2014.05.114
(2014)Doi:10.1021/jo00096a001
(1994)Doi:10.1016/0968-0896(96)00141-1
(1996)