Ketone-directed peracid epoxidation of cyclic alkenes

DOI: 10.1039/p19960001373

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1373 - 1380 (1996)

Update date:2022-08-05

Topics:

Authors:

Armstrong, Alan

Barsanti, Paul A.

Clarke, Paul A.

Wood, Anthony

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/p19960001373

Ketone carbonyl groups are shown to direct the peracid epoxidation of cyclic alkenes with greater selectivity than that displayed by esters. An ¹⁸O labelling study is used to show that a dioxirane intermediate is not involved in these reactions.

Full text of DOI:10.1039/p19960001373

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-Cyclohex-2-enyl-5-methylhexan-2-one

Cas No:158233-84-2

R&D Labs maybe for 158233-84-2

Taizhou KEDE Chemical.Co.,Ltd.

Contact:86-576-84613060

Address:Jiangkou Chemical Zoon
Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
JIANGXI XINXIN CHEMICAL CO., LTD.

Contact:86-15957176628

Address:INDUSTRY ROAD 1, INDUSTRIAL PARK, HEKOU TOWN,YANSHAN COUNTY, JIANGXI PROVINCE, CHINA
Suzhou Jingye Medicine & Chemical Co., Ltd

Contact:+86-512-66658588

Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China

Relevant to this article

Conformational Preferences of a Tropos Biphenyl Phosphinooxazoline-a Ligand with Wide Substrate Scope

Doi:10.1021/acscatal.5b02766
(2016)
Solvent-dependent Baylis-Hillman reactions for the synthesis of 3-benzyl-3-hydroxyoxindoles and benzo-δ-sultams

Doi:10.1016/j.tet.2014.02.038
(2014)
Erratum: Synthetic exploitation of halogenated alkenes containing an electron-withdrawing group: Synthesis of α-chlorohydrazones and ketene aminals by regiospecific reactions of in situ generated imide chlorides (Tetrahedron Letters (2014) 55 (2085-2089))

Doi:10.1016/j.tetlet.2014.05.114
(2014)
Oxidative Rearrangement of 4-Hydroxy-2-cyclobutenone. A New Route to Highly Substituted Furanones from Squaric Acid

Doi:10.1021/jo00096a001
(1994)
3-Carboxy-20-keto steroids are dual uncompetitive inhibitors of human steroid 5α-reductase types 1 and 2

Doi:10.1016/0968-0896(96)00141-1
(1996)
Design, synthesis and biological evaluation of 4-Amino-N-(4-aminophenyl) benzamide analogues of quinoline-based SGI-1027 as inhibitors of DNA methylation

Doi:10.1002/cmdc.201300420
(2014)

Article Doi