Two Types of Stereocontrol in the Formation of Spiro Skeletons via a Carbonyl Ene Reaction and a Palladium-catalysed Carbonyl Allylation: a Formal Synthesis of (+)-Perhydrohistrionicotoxin

DOI: 10.1039/c39940001835

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1835 - 1836 (1994)

Update date:2022-09-26

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Authors:

Maezaki, Naoyoshi

Fukuyama, Hidenori

Yagi, Suguru

Tanaka, Testuaki

Iwata, Chuzo

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Article abstract of DOI:10.1039/c39940001835

Different stereocontrol is observed in the formation of spiro skeletons via a carbonyl ene reaction and a palladium-catalysed carbonyl allylation, and a formal synthesis of (+)-perhydrohistrionicotoxin is accomplished.

Full text of DOI:10.1039/c39940001835

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