Chemical and Pharmaceutical Bulletin p. 994 - 996 (1994)
Update date:2022-07-29
Topics:
Yoshikawa
Yokokawa
Okuno
Murakami
Myriocin (thermozymocidin, ISP-I), which was known to exhibit several interesting biological properties such as potent immunosuppressive and antifungal activities, and a new analog Z-myriocin were synthesized from 2-deoxy-D-glucose. This synthetic pathway comprises a stereoselective formation of the chiral α,α-disubstituted amino acid structure in myriocin and Z-myriocin from the isopropylidene six-membered ketone by using a modified Darzen reaction as its key step.
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