cis-Ammine(benzoylhydrazine-N)dichloroplatinum(II)

DOI: 10.1107/S0108270194001757

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 1214 - 1217 (1994)

Update date:2022-08-02

Topics:

Authors:

Macicek, Josef

Dodoff, Nicolay

Spassovska, Nadejda

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Article abstract of DOI:10.1107/S0108270194001757

In the title compound, cis-ammine(benzohydrazide-N')dichloroplatinum(II), cis-, the benzoylhydrazine ligand is bonded to the Pt atom through its amino group.The Pt-Cl and Pt-N distances are in the ranges 2.293(5)-2.318(5) and 2.01(1)-2.08(1) Angstroem, respectively.The arrangement of molecules in the monoclinic unit cell approximates P2₁/c space-group patterns; however, the true space-group symmetry is P2₁.The two crystallographically independent molecules have significantly different conformations about the Pt-N(hydrazine) bond.The structure is held together by a complicated network of N-H...O and N-H...Cl hydrogen bonds.

Full text of DOI:10.1107/S0108270194001757

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