Tetrahedron Letters p. 6469 - 6472 (1994)
Update date:2022-08-03
Topics:
Luengo, Juan I.
Rozamus, Leonard W.
Holt, Dennis A.
The reaction of rapamycin (1) with different reductive agents has been studied.As expected, the C14 ketone of the "tricarbonyl" unit is the most electrophilic center in the molecule and could be selectively converted to either the alcohol (Zn/AcOH or DIBA
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Doi:10.1021/jo00092a019
(1994)Doi:10.1021/jo2004007
(2011)Doi:10.1016/j.jorganchem.2009.09.028
(2010)Doi:10.1080/15257779508012499
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(2011)Doi:10.1246/cl.1994.1961
(1994)
