The effect of zinc(II)bromide on the reduction of a chiral, non-racemic, benzylidene sulphinamide derived from a recoverable, cyclic sulphinamide

DOI: 10.1016/S0040-4039(00)77091-2

Source and publish data:

Tetrahedron Letters p. 5303 - 5306 (1994)

Update date:2022-08-03

Topics:

Authors:

Hose Hose

Hose, David R. J.

Wills Wills

Wills, Martin

Raynham Raynham

Raynham, Tony

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Article abstract of DOI:10.1016/S0040-4039(00)77091-2

The addition of zinc(II)bromide reverses the diastereoselectivity of the diisobutyl-aluminium hydride (DIBAL-H) reduction of benzylidene sulphinamide R((S))R-(-)-4. The same reversal is not observed in the reactions of analogues lacking an amide side chai

Full text of DOI:10.1016/S0040-4039(00)77091-2

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