3,4,6-Tri-O-benzyl-α-D-arabino-hexopyranos-2-ulosyl Bromide: A Versatile Glycosyl Donor for the Efficient Generation of β-D-Mannopyranosidic Linkages

DOI: 10.1021/jo00101a035

Source and publish data:

Journal of Organic Chemistry p. 6728 - 6734 (1994)

Update date:2022-07-29

Topics:

Authors:

Lichtenthaler, Frieder W.

Schneider-Adams, Thomas

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Article abstract of DOI:10.1021/jo00101a035

An expedient four-step sequence is described for the conversion of acetobromoglucose into the title 2-oxohexosyl ("ulosyl") bromide 4.Due to its O-benzyl protection, 4 is considerably more reactive than its acylated analogs 1-3: Ag2CO3-promoted glycosidat

Full text of DOI:10.1021/jo00101a035

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