Preparation of both enantiomers of 2-methyl-3-hydroxythioesters based on chiral Lewis acid-controlled synthesis

DOI: 10.1016/0040-4020(96)00251-7

Source and publish data:

Tetrahedron p. 7277 - 7286 (1996)

Update date:2022-08-04

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Authors:

Kobayashi, Shu

Horibe, Mineko

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Article abstract of DOI:10.1016/0040-4020(96)00251-7

Both enantiomers of 2-methyl-3-hydroxythioesters have been synthesized by using chiral tin(II) Lewis acid-mediated aldol reactions of (Z)-1-ethylthio-1-trimethylsiloxypropene (4) with aldehydes, based on chiral Lewis acid-controlled synthesis. The key to

Full text of DOI:10.1016/0040-4020(96)00251-7

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Product name:S-ethyl (2R,3S)-2-(tert-butyldimethylsiloxy)-3-hydroxy-3-phenylpropanethioate

Cas No:159573-36-1

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