Tetrahedron p. 2683 - 2694 (1981)
Update date:2022-07-29
Topics:
Vincens, M.
Dumont, C.
Vidal, M.
The identification of E- and Z-2-alkyl-3-ethylidenecyclopropane having a functional group (ketone, ester, alcohol) at C-1 of the ring, is realized by chemical means and by NMR induced shift using Eu(dpm)3.These structure assignments show that the cyclopropene ester, ketone, alcohol double bond migration in basic media leads preferentially to the E-configuration; the stereoselectivity may reach 90percent.Moreover, the prototropy is regiospecific and stereospecific compared to the ring.
View MoreZiBO KuoDing Trade company Ltd
website:http://www.sdzbkd.com
Contact:86-13361591822
Address:GongQingTuan road
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)
Contact:+86-571-56880228
Address:15F Guodu development Building, NO.182 Zhaohui Road
Contact:+86-29-88710656
Address:South Tai bai Road, High Tech Development Zone, Xi'an China
Contact:86-371-63655023
Address:No.85,jinshui road,zhengzhou,China
Quzhou Aokai Chemical Co., Ltd.
Contact:86-570-3032832
Address:NO.16 , Laodong Road,Quzhou City, Zhejiang Province,China
Doi:10.1002/ejoc.201301227
(2014)Doi:10.1016/S0040-4020(01)80690-6
(1994)Doi:10.1016/j.tetlet.2014.03.021
(2014)Doi:10.1021/jo00017a041
(1991)Doi:10.1021/op200275d
(2012)Doi:10.1039/c1cc14995d
(2011)
