Tetrahedron Letters p. 3005 - 3008 (1994)
Update date:2022-08-03
Topics:
Shankar
McCombie
In an attempt to construct the unique N,N′-bidentate glycosyl linkage found in the Staurosporine 1 class of natural products, the first example of an acid catalyzed 2,6-condensation of an activated pyran with indolocarbazole 4 is reported. In pursuit of the real system, a variety of glycals were reacted with indolocarbazole 4. Formation of novel unexpected products (B/C) with 1,3-connections along with the expected product (A) and its' synthetic transformation to a potentially useful intermediate 24 are detailed.
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Doi:10.1016/0040-4039(94)80116-9
(1994)Doi:10.1248/cpb.42.1258
(1994)Doi:10.1039/c4ob00206g
(2014)Doi:10.1016/j.tetasy.2014.02.004
(2014)Doi:10.1021/ja00137a021
(1995)Doi:10.1016/0008-6215(94)00189-8
(1994)
