Convenient synthesis of pyruvate acetals of carbohydrates by coupling of trialkylsilylated diols and pyruvates

DOI: 10.1016/S0040-4020(01)89567-3

Source and publish data:

Tetrahedron p. 12143 - 12158 (1994)

Update date:2022-09-26

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Authors:

Hiruma, Kazumi

Tamura, Jun-Ichi

Horito, Sigeomi

Yoshimura, Juji

Hashimoto, Hironobu

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Article abstract of DOI:10.1016/S0040-4020(01)89567-3

Hexopyranoside diols, mainly 4,6-diols with α-gluco, β-gluco, α-galacto, β-galacto, and α-manno configurations could be converted effectively (40-74% yields), to the corresponding pyruvate acetals by the coupling of the O-trialkylsilylated, namely, O-TBDM

Full text of DOI:10.1016/S0040-4020(01)89567-3

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