Reaction of enaminones with thiacumulenes

Article abstract of DOI:10.1080/10426509808032471

Enaminones 2, easily prepared from the corresponding sodium salts of ss-ketoaldehydes 1 and hydrochlorides of primary amines, react with carbon disulfide/ sodium hydride to give dithiocarbamates 3 after alkylation. In a similar way thiocarbamoylation yields isothioureas 4. The ¹³C NMR parameters of 2, 3 and 4 show significant low- and high-field shifts of the C-1 and C-2 signals, respectively.

Full text of DOI:10.1080/10426509808032471

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Phosphorus, Sulfur, and Silicon and the
Related Elements
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REACTION OF ENAMINONES WITH
THIACUMULENES
Swapan Kumar Chatterjee a & Wolf-Dieter Rudorf a
a Institute of Organic Chemistry, Martin Luther University Halle-
Wittenberg , Kurt-Mothes-Str. 2, D-06099, Halle, Saale, Germany
Published online: 24 Sep 2006.
To cite this article: Swapan Kumar Chatterjee & Wolf-Dieter Rudorf (1998) REACTION OF ENAMINONES
WITH THIACUMULENES, Phosphorus, Sulfur, and Silicon and the Related Elements, 133:1, 251-266, DOI:
10.1080/10426509808032471
To link to this article: http://dx.doi.org/10.1080/10426509808032471
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