Novel synthesis of nitrogen heterocycles using zirconium-promoted reductive cyclization

DOI: 10.1021/jo00098a023

Source and publish data:

Journal of Organic Chemistry p. 5643 - 5649 (1994)

Update date:2022-08-05

Topics:

Authors:

Mori Mori

Uesaka Uesaka

Saitoh Saitoh

Shibasaki

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Article abstract of DOI:10.1021/jo00098a023

Perhydroindole derivatives were prepared from enynes using zirconium-promoted reductive cyclization. The zirconacycles derived from enynes 1 were treated with iodine, isonitriles, oxygen, and carbon monoxide to give various heterocycles. The carbon-zirconium bonds of the zirconacycle could be selectively cleaved by different reagents.

Full text of DOI:10.1021/jo00098a023

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