Journal of Organic Chemistry p. 5643 - 5649 (1994)
Update date:2022-08-05
Topics:
Mori
Uesaka
Saitoh
Shibasaki
Perhydroindole derivatives were prepared from enynes using zirconium-promoted reductive cyclization. The zirconacycles derived from enynes 1 were treated with iodine, isonitriles, oxygen, and carbon monoxide to give various heterocycles. The carbon-zirconium bonds of the zirconacycle could be selectively cleaved by different reagents.
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