Tetrahedron p. 12953 - 12958 (1994)
Update date:2022-08-04
Topics:
Lardicci, Luciano
Malanga, Corrado
Balzano, Federica
Menicagli, Rita
In the presence of a catalytic amount of Ni°, 2-methyl-1,3-dioxep-4-ene (1) reacts with secondary halogen magnesioamides (2) to give mixtures of 4-aminobut-2-enols (3) and 2-aminobut-3-enols (4), arising from α- or γ-substitution to 1. The stereo and regiochemistry of the reaction is closely related to the structures of 2.
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