Journal of the Chemical Society. Perkin transactions I p. 95 - 96 (1995)
Update date:2022-08-04
Topics:
Huang, Zhi-Zhen
Huang, Xian
Huang, Yao-Zeng
Acyl(phenylselanyl)methylidene(triphenyl)-λ5-arsanes 3 have been synthesized by treating acylmethylidene(triphenyl)-λ5-arsanes 1 with phenylselanyl iodide 2; α-selanylarsonium ylides 3 are sufficiently reactive to undergo Wittig-type reactions, affording a novel method for the stereoselective synthesis of (Z)-α-phenylselanyl α,β-unsaturated ketones 6.
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