Tetrahedron Letters p. 8881 - 8882 (1994)
Update date:2022-08-03
Topics:
Blanco
Blanco, Francisco J.
Cuadrado
Cuadrado, Purificacion
Gonzalez
Gonzalez, Ana M.
Pulido
Pulido, Francisco J.
Fleming
Fleming, Ian
Allene 1 reacts at -40*C with the phenyldimethylsilylcopper reagent 6, with the opposite regioselectivity to that shown by the corresponding silylcuprate reagent 2, to give allylsilanes 7 and 10-15 rather than vinylsilanes.
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