Organic Letters
Letter
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anti-1,4-adducts gave π-conjugated polymers, which could act as
sensors of explosive species. This highly efficient synthesis
method provides new approaches to obtaining solid-state
emissive materials. Further studies will focus on the photo-
physical properties of the π-conjugated polymers in condensed
phases and their applications as fluorescent materials.
ASSOCIATED CONTENT
* Supporting Information
■
S
The Supporting Information is available free of charge on the
Experimental procedures, product characterizations, and 1H,
13C and 19NMR spectra (PDF)
2003, 59, 9039. (h) Stuhlmann, F.; Jaschke, A. J. Am. Chem. Soc. 2002,
̈
124, 3238. (i) Sanyal, A.; Snyder, J. K. Org. Lett. 2000, 2, 2527.
(j) Bachmann, W. E.; Scott, L. J. Am. Chem. Soc. 1948, 70, 1458.
(8) (a) Smith, N. M.; Iyer, K. S.; Corry, B. Phys. Chem. Chem. Phys.
X-ray data for compound 10 (CIF)
X-ray data for compound 12a (CIF)
X-ray data for compound 13a (CIF)
2014, 16, 6986. (b) Nikitin, K.; Muller-Bunz, H.; McGlinchey, M. J.
̈
Organometallics 2013, 32, 6118. (c) Yoshizawa, M.; Tamura, M.; Fujita,
M. Science 2006, 312, 251. (d) Klanderman, B. J. Am. Chem. Soc. 1965,
87, 4649.
AUTHOR INFORMATION
Corresponding Author
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(9) (a) Murase, T.; Horiuchi, S.; Fujita, M. J. Am. Chem. Soc. 2010, 132,
2866. (b) Fort, E. H.; Donovan, P. M.; Scott, L. T. J. Am. Chem. Soc.
2009, 131, 16006. (c) Biermann, D.; Schmidt, W. J. Am. Chem. Soc.
1980, 102, 3163.
Notes
The authors declare no competing financial interest.
(10) For examples containing a Diels−Alder reaction of naphthalene
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ARKIVOC 2004, 12, 70. (b) He, Y.; Junk, C. P.; Lemal, D. M. Org. Lett.
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(11) For Diels−Alder reaction of phenanthrene derivatives, see: Pirkle,
W. H.; Liu, Y. J. Chromatogr. A 1996, 736, 31.
ACKNOWLEDGMENTS
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This research was financially supported by the National Natural
Science Foundation (No. 91227202) and the National Basic
Research Program (2013CB933500) of the Ministry of Science
and Technology of China.
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