Rhodium-mediated stoichiometric P=C bond cleavage and catalytic isomerization in phosphacumulenes

DOI: 10.1021/om00001a007

Source and publish data:

Organometallics p. 17 - 19 (1995)

Update date:2022-07-30

Topics:

Authors:

David, Marie-Anne

Paisner, Sara N.

Glueck, David S.

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Article abstract of DOI:10.1021/om00001a007

Reaction of Rh(PCy₃)₂Cl (4a, Cy = cyclo-C₆H₁₁) with the phosphacumulenes Mes*P=C=X (X = O (1), X = NPh (2); Mes* = 2,4,6-(t-Bu)₃C₆H₂) results in P=C bond cleavage to form [2,4-(t

Full text of DOI:10.1021/om00001a007

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