Tetrahedron Letters p. 843 - 846 (1994)
Update date:2022-08-03
Topics:
VanNieuwenhze, Michael S.
Barry Sharpless
The asymmetric dehydroxylation of several cis allylic alcohols is reported. The reactions proceed with moderate to good enantioselectivity. The enhanced enantioselection observed relative to other cis-olefin classes is believed to be dependent on the presence of the free hydroxyl group. A cis-homoallylic alcohol also gave a useful level of enantioselection in the AD.
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