Chemistry Letters p. 175 - 176 (1998)
Update date:2022-08-03
Topics:
Haider, Syed Shabbir
Tanaka, Masatoshi
Alam, Md Khorshed
Nakajima, Shuhei
Baba, Naomichi
Shimizu, Sakayu
A phosphatidylcholine 9 bearing icosadienoyl and docosahexaenoyl groups at the 1-and 2-positions respectively was synthesized. The synthetic route involves carbon chain elongation of linoleic acid via malonic ester synthesis, preparation of lyso-phosphatidylcholine via lipase-catalyzed mono-acylation of 2-O-methoxyethoxymethylglycerol and phosphodiester synthesis, and finally DCC-mediated esterification.
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